I already covered one application that can edit that Places Bar in Windows but it’s never bad to have additional applications available that can do the same in case one of them disappears from the Internet. (yes that can happen).
Once you start the PlacesBar Tweaker application you see the five current places on the left side. Those places can be moved around to arrange them in a different order. More important than that is obviously the ability to change a location into a different one.